The procedures for patching the zorb balls as below for reference.
1) Have the ball deflated and completely cleaned before patching.
2) Cut a suitable and clean piece of spare material.
3) After the cleaning dry out, use the glue on the spare material and stick it well covering the small hole.
4) If possible, use the hot hair drier to blow and it helps to strengthen the pasting.
5) Leave it not less then 30 minutes till it dries well.
6) Re-inflate it and try
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Zorb Ball Repair